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This article was automatically translated from the original Turkish version.

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Sodium Chloride (NaCl)

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Sodyum Klorür

Chemical Formula
NaCl
Appearance
Whitecrystalline solid
Molecular Weight
58.44 g/mol
pH Value
7 (Neutral)
Structure
Ionic (FCC lattice)
Ionic Structure
Composed of Na⁺ and Cl⁻ ions
Type of Salt
Neutral salt
Formation
NaOH + HCl → NaCl + H₂O
Areas of Use
Foodmedical solutionschlor-alkali productionwater treatmentroad de-icing

Sodium chloride (NaCl) is a crystalline, white, ionic compound composed of sodium (Na⁺) and chloride (Cl⁻) ions. In daily life it is known as “table salt” and holds significant biological and industrial importance. Chemically, it is a neutral salt formed by the reaction of a strong acid with a strong base.


NaCl occurs naturally in high concentrations both in underground salt deposits and in seawater. Major producers include the United States, China, India, and Canada.

History

Sodium chloride, or table salt, is one of the oldest and most strategic substances in human history. The preservative and flavor-enhancing properties of salt made it essential for pre-agricultural societies. Archaeological evidence indicates that salt was extracted in Chinese settlements as early as 6000 BCE. In China’s Sichuan region, the use of salt wells dates back to the 3rd millennium BCE, and early salt distillation techniques were developed there.


In ancient Rome, salt became an economically and socially significant commodity. Part of Roman soldiers’ pay was rendered in salt; this practice is the origin of the English word “salary.” The Romans prioritized the construction of roads and transport routes for salt, as evidenced by ancient roads named “Via Salaria” (Salt Road).


Throughout the Middle Ages, salt remained a fundamental component of trade and taxation. In India, salt was tightly controlled both during the Mughal period and under British colonial rule; Gandhi’s famous 1930 Salt March became a symbolic act of resistance against these restrictions.


In Anatolia, salt production and distribution have been under state control since the Hittite era. During the Ottoman Empire, salt mines were declared state property (miri mülk) and brought under central administration. This practice underscores the long historical continuity of salt’s strategic importance.


From the late 19th century onward, industrial development transformed sodium chloride from merely a foodstuff into a fundamental raw material for the chemical industry. Its role in the chlor-alkali industry has further enhanced its economic and technological value in the modern era.

Physical and Chemical Properties

Sodium chloride (NaCl) is a crystalline, white solid with an ionic structure. At room temperature, it remains stable and consists of equal numbers of sodium (Na⁺) and chloride (Cl⁻) ions. It has a face-centered cubic crystal structure, in which each sodium ion is surrounded by six chloride ions. The molecular weight of sodium chloride is 58.44 g/mol. Its melting point is 801 °C and its boiling point is 1,413 °C. At 25 °C, its density is approximately 2.165 g/cm³. It is highly soluble in water, with about 357 grams dissolving in one liter at 20 °C. This high solubility enhances the ionic conductivity of its solution, making it effective in both biological and industrial systems.


Chemically, sodium chloride is a neutral salt formed by the reaction of a strong acid, hydrochloric acid (HCl), with a strong base, sodium hydroxide (NaOH). This neutralization reaction produces NaCl and water. Consequently, a 1 molar aqueous solution of NaCl exhibits a pH of approximately 7 and displays neutral characteristics. It fully dissociates in water, providing electrical conductivity. Chemically stable under normal conditions, it does not react readily but melts before vaporizing at high temperatures. It may react with strong oxidizing agents, particularly concentrated sulfuric acid. All these properties have made sodium chloride not only table salt but also a fundamental chemical raw material with broad industrial applications.

<span class="katex"><span class="katex-html" aria-hidden="true"><span class="base"><span class="strut" style="height:1em;vertical-align:-0.25em;"></span><span class="mord mathnormal" style="margin-right:0.10903em;">N</span><span class="mord mathnormal">a</span><span class="mord mathnormal" style="margin-right:0.02778em;">O</span><span class="mord mathnormal" style="margin-right:0.08125em;">H</span><span class="mopen">(</span><span class="mord mathnormal">ba</span><span class="mord mathnormal" style="margin-right:0.04398em;">z</span><span class="mclose">)</span><span class="mspace" style="margin-right:0.2222em;"></span><span class="mbin">+</span><span class="mspace" style="margin-right:0.2222em;"></span></span><span class="base"><span class="strut" style="height:1em;vertical-align:-0.25em;"></span><span class="mord mathnormal" style="margin-right:0.08125em;">H</span><span class="mord mathnormal" style="margin-right:0.01968em;">Cl</span><span class="mopen">(</span><span class="mord mathnormal">a</span><span class="mord mathnormal">s</span><span class="mord mathnormal">i</span><span class="mord mathnormal">t</span><span class="mclose">)</span><span class="mspace" style="margin-right:0.2778em;"></span><span class="mrel">→</span><span class="mspace" style="margin-right:0.2778em;"></span></span><span class="base"><span class="strut" style="height:1em;vertical-align:-0.25em;"></span><span class="mord mathnormal" style="margin-right:0.10903em;">N</span><span class="mord mathnormal">a</span><span class="mord mathnormal" style="margin-right:0.01968em;">Cl</span><span class="mopen">(</span><span class="mord mathnormal">t</span><span class="mord mathnormal">u</span><span class="mord mathnormal" style="margin-right:0.04398em;">z</span><span class="mclose">)</span><span class="mspace" style="margin-right:0.2222em;"></span><span class="mbin">+</span><span class="mspace" style="margin-right:0.2222em;"></span></span><span class="base"><span class="strut" style="height:0.8333em;vertical-align:-0.15em;"></span><span class="mord"><span class="mord mathnormal" style="margin-right:0.08125em;">H</span><span class="msupsub"><span class="vlist-t vlist-t2"><span class="vlist-r"><span class="vlist" style="height:0.3011em;"><span style="top:-2.55em;margin-left:-0.0813em;margin-right:0.05em;"><span class="pstrut" style="height:2.7em;"></span><span class="sizing reset-size6 size3 mtight"><span class="mord mtight"><span class="mord mtight">2</span></span></span></span></span><span class="vlist-s">​</span></span><span class="vlist-r"><span class="vlist" style="height:0.15em;"><span></span></span></span></span></span></span><span class="mord mathnormal" style="margin-right:0.02778em;">O</span></span></span></span>

Sodium Chloride Neutralization Reaction

Applications

  • Food and Preservation Technologies: Consumed directly as table salt. Widely used in the food industry as a flavor enhancer and preservative. In processes such as brining, pickling, and meat curing, it slows microbial growth and extends shelf life.


  • Industrial Production and Chemistry: NaCl is a primary feedstock for the production of chlorine (Cl₂) and sodium hydroxide (NaOH) in the chlor-alkali process. It is also used as a processing aid in the soap, plastic, paper, and dye industries. It is employed in regenerative water softening systems for ion exchange. Additionally, it functions as an anti-caking agent in detergents and as a filler in plastic manufacturing.


  • Health and Medical Applications: Serves as a key component in medical solutions such as physiological saline. It helps maintain electrolyte balance. Used in mouthwashes, wound cleansing, and eye baths for oral and dental health. Classified by the U.S. Food and Drug Administration (FDA) as “Generally Recognized As Safe” (GRAS).

Biological Role and Importance

Sodium and chloride ions regulate the osmotic balance of extracellular fluid. They play vital roles in muscle contraction, nerve transmission, and blood pressure control. Since the body cannot synthesize them, they must be obtained externally. Deficiency can lead to hyponatremia, while excess may cause hypertension and other disorders.

Environmental Impact

When used for de-icing roads and sidewalks, salt can lead to sodium accumulation in soil and disrupt the ionic balance of surface waters. Therefore, controlled environmental release is essential. It can also have toxic effects on vegetation and contribute to metal corrosion in infrastructure systems.

Author Information

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Authorİsmail OrçanDecember 4, 2025 at 10:33 AM

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Contents

  • History

  • Physical and Chemical Properties

  • Applications

  • Biological Role and Importance

  • Environmental Impact

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